Self-assembly of two New Zinc coordination Polymers Based on N-[(3-Pyridine)-sulfonyl]amino Acid: Structure and Fluorescence

  • Jiang Yi-Min College of Chemistry and Pharmacy, Guangxi Normal University, Guilin, 541004, P.R. China
  • Pei Luo College of Chemistry and Pharmacy, Guangxi Normal University, Guilin, 541004, P.R. China
  • Shi-Xiong Li College of Chemistry and Pharmacy, Guangxi Normal University, Guilin, 541004, P.R. China. College of Environment and Energy, South China University of Technology, Guangzhou, 510006, P. R. China

Abstract

Two new zinc coordination polymers based on N-[(3-Pyridine)-sulfonyl]amino acid ligand have been synthesized and characterized by single-crystal X-ray diffraction and elemental analysis. The results show that the 1 is a two-dimensional structure polymer and synthesized under room temperature condition; the 2 is a three-dimensional structure polymer and synthesized under hydrothermal synthesis conditions. These two structures are formed by 4,4'-dipyridy and 4,4'-azpy for 1 and 2, respectively. A structural comparison of these two polymers suggests that different reaction temperatures play important role in the construction of resulting architectures for 1 and 2. Fluorescence measurements show that 1 has medium fluorescent emission at 374 nm and 2 has medium fluorescent emission at 438 nm.

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Published
2016-07-19
How to Cite
Yi-Min, J., Luo, P., & Li, S.-X. (2016). Self-assembly of two New Zinc coordination Polymers Based on N-[(3-Pyridine)-sulfonyl]amino Acid: Structure and Fluorescence. Communications in Inorganic Synthesis, 4(3). https://doi.org/10.21060/cis.v4i3.2391
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Artículos