1.2.4. Synthesis, crystal structure and thermal stability property of Ni(aze)(4,4′ –bipy)(H2O) based on longer-spanning azelaic acid and 4,4′ -bipyridine ligands

Ge Song, Feng Ying Bai*, Yan Xie, Yong Heng Xing.


Abstract: One new three-dimensional (3D) supramolecular

longer-spanning azelaic acid (H2aze) complex: Ni(aze)(4,4

bipy)(H2O) (4,4-bipy = 4,4-bipyridine) has been synthesized

using hydrothermal conditions and characterized by elemental

analysis, IR spectroscopy, UV spectrum, powder X-ray diffraction,

TG analysis and single crystal X–ray diffraction. Structural

analysis reveals that the title complex is six-coordinate

and connected by the azelaic acid and 4,4-bipy ligands to generate

a 2D planar structure, further linked through the interaction

of hydrogen bond of C–H···O to form a 3D supramolecular

structure .

Supporting information: FT-IR, UV-Vis, X-Ray, Cif file

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