1.2.3. Synthesis and Structural Characterization of [Co0.5(bimb)1.5] n·nClO4 (bimb =1,4-bis(imidazol-1-yl)-butane)

Xiu-Mei Li*, Jian-Ye Ji, Zhi-Tao Wang, Yan-Ling Niu


Abstract: A new cobalt(II) coordination polymer, namely [Co0.5

(bimb)1.5]n·nClO4 (bimb =1,4-bis(imidazol-1-yl)-butane)  (1), has

been prepared and fully characterized by single-crystal X-ray

diffraction, elemental analyses, IR spectroscopy and X-ray powder

diffraction pattern analysis (PXRD). Of the compound, the

Co(II) center is octahedral coordinated with bimb serving as a

bridging ligand by employing six N-donor to coordinate with

the Co(II) center. It exbihits three-dimensional network structure

via bimb ligands.

Supporting information: CIF file.

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